Thursday, May 17, 2012

2. Copaiba

Synonyms Balsam copaiba; Balsam capivi; Jesuit’s Balgar.
Biological Source Copaiba is the oleoresin obtained from the South American species of Copaifera (Copaiba) belonging to family: Leguminosae.
Preparation The oleoresin is collected by incisions made on the trunk of various species of Copaifera Linn., (a method similar to colophony described under Section 2.7).
Characteristic Features It is a transparent, viscid to pale-yellow to brownish-yellow liquid. It has a peculiar odour and bears a nauseating, bitter and acrid taste. Its acid number in 28-95 and d 0.930-0.995. It is practically insoluble in water, but soluble in benzene, chloroform, ether, oils, CS2, absolute ethanol, petroleum ether and partly soluble in 95% ethanol. It is incompatible with mineral acids, magnesia and water. Capaiba is found to contain a volatile oil, resin acids (e.g., capaivic acid and illurinic acid), besides a small quantity of a bilter principle and a fluorescent substance.
The major constituents of the volatile oil are cryophyllene, isocaryophyllene and that of the resin acid is β-metacapaivic acid as given below:


cryophyllene, isocaryophyllene
Uses
1. It is used in varnishes.
2. It is also employed for removing old oil varnish from oil paintings.
3. It is used in the manufacture of photographic paper.

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